程瑞华,工学博士,副教授,硕士生导师。
E-mail:rhcheng@gdut.edu.cn
教育经历:
中国科学院大连化学物理研究所,2000.9-2006.12
工业催化专业,工学博士(硕博连读),导师:张涛研究员、院士
内蒙古大学,1996.9-2000.7
化学基地专业,理学学士,赵薇副教授
工作经历:
广东工业大学生物医药学院制药工程系,副教授,2021.10-至今
华东理工大学化学化工学院化学工程系,讲师,副教授,2007.9-2021.9
美国加州大学伯克利分校生物与化学工程学院Jeffrey A. Reimer教授课题组,访问学者,2013.9-2015.1
研究方向:
从事药物合成、高分子合成、催化剂开发及工艺开发研究。目前主要研究方向有:
(1)原料药及中间体合成用(手性)催化剂开发及催化机理研究,药物连续流动合成技术与工程。
(2)生物药用高分子材料,包括药用辅料、可降解药物传输/释放控制载体、抗菌水凝胶、刺激响应水凝胶、杀菌医用敷料的设计、合成与性能研究。
(3)二氧化碳的高效转化和利用,聚(氨)酯的催化合成。
(4)新型烯烃聚合/齐聚催化体系的开发、机理研究及应用;高性能聚烯烃产品,尼龙12单体、聚异丁烯等开发与应用。
主要科研项目:
主持和作为技术骨干参加了多项国家、省部级课题的研究工作。负责上海市浦江人才项目1项;国家自然科学青年基金1项;2013、2010年度中央高校基本科研业务费专项资金2项;中石油研究院横向项目2项;万华化学公司横向项目多项。其中承担的“丁二烯三聚环合成环十二碳”单体项目,已在万华化学率先实现了高性能尼龙-12的国产化,打破了以赢创为代表的海外公司在高端长链尼龙领域的垄断。同时作为主要完成人参与多项国家、省部级及国内外企业横向项目。
论文发表:
1. Zhang, H.; Liu, Y.; Zhang, L.; Wang, X.; Sun, H.; Liu, C.; Ye, J.; Cheng, R., Direct reductive amination from ketones, aldehydes to synthesize amines usingN,S-dual doped Co/C catalyst.Catal. Lett.2022, doi: 10.1007/s10562-021-03911-2.
2. Wang, J.; Liu, C.; Cao, L.; Xiong, Y.; Ye, J.; Liu, Z.; Cheng, R., Theoretical investigation of mechanism and ligand effects on half-sandwich iridium complexes for direct reductive amination.Mol. Catal.2022,517, 112050.
3. Zou, C.; Yang, L.; Zhang, L.; Liu, C.; Ma, Y.; Song, G.; Liu, Z.; Cheng, R.; Ye, J., Enantioselective vinylogous conia-ene reaction catalyzed by a disilver(i)/bisdiamine complex.ACS Catal.2021,11(12), 6865-6871.
4. Sun, M.; Yang, J.; Fu, Y.; Liang, C.; Li, H.; Yan, G.; Yin, C.; Yu, W.; Ma, Y.; Cheng, R.; Ye, J., Continuous flow process for the synthesis of betahistine via aza-Michael-type reaction in water.Org. Process Res. Dev.2021,25(5), 1160-1166.
5. Sun, M.; Liang, C.; Shen, X.; Li, J.; Cheng, R.; Ye, J., Continuous flow science in an undergraduate teaching laboratory: synthesis of ethylene glycol diacetate using heterogeneous catalysts in continuous flow.J. Chem. Educ.2021,98(2), 572-576.
6. Sun, M.; Li, J.; Liang, C.; Shan, C.; Shen, X.; Cheng, R.; Ma, Y.; Ye, J., Practical and rapid construction of 2-pyridyl ketone library in continuous flow.J. Flow Chem.2021,11(2), 91-98.
7. Ma, Y.; Hong, J.; Yao, X.; Liu, C.; Zhang, L.; Fu, Y.; Sun, M.; Cheng, R.; Li, Z.; Ye, J., Aminomethylation of aryl bromides by nickel-catalyzed electrochemical redox neutral cross coupling.Org. Lett.2021,23(24), 9387-9392.
8. Liu, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Ligand-induced product switching between 4-methyl-1-pentene and 2-methyl-1-pentene in bis(imino)pyridine/v(iii)-catalyzed propylene dimerization: cossee-arlman versus metallacycle mechanism.Organometallics2021,40(11), 1682-1691.
9. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic studies of reduction and initiation over the vanadium-oxide polyethylene catalyst.J. Phys. Chem. C2021,125(4), 2393-2402.
10. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic study of vanadium-modified and sulfation-modified Phillips catalyst.Mol. Catal.2021,513, 111777.
11. Liang, C.; Sun, M.; Shen, X.; Shan, C.; Wang, W.; Cheng, R.; Ye, J., Three-step one-pot process of 3-methyl-5-benzofuranol from amine, aldehydes, andp-benzoquinone.Org. Process Res. Dev.2021,25(4), 810-816.
12. Feng, Z.; Wu, L.; Dong, H.; Liu, B.; Cheng, R., Copolyesters of ε-caprolactone and L-lactide catalyzed by a tetrabutylammonium phthalimide-N-oxyl organocatalyst.RSC Adv.2021,11(31), 19021-19028.
13. Wu, L.; Liu, W.; Ye, J.; Cheng, R., Fast cyclotrimerization of a wide range of isocyanates to isocyanurates over acid/base conjugates under bulk conditions.Catal. Commun.2020,145, 106097.
14. Tong, Y.; Cheng, R.; Yu, L.; Liu, B., New strategies for synthesis of amino-functionalized poly(propylene carbonate) over SalenCo(III)Cl catalyst.J. Polym. Sci.2020,58(9), 1325-1337.
15. Liu, Y.; Zhang, R.; Ren, H.; Liu, Y.; Ling, S.; Zhang, H.; Liu, B.; Cheng, R., CrV bimetallic Phillips catalyst prepared by citric acid-assisted impregnation on ethylene polymerization.Macromol. Chem. Phys.2020,221(10), 2000010.
16. Liu, K.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic study on the effects of co-catalyst on ethylene polymerization over supported vanadocene catalyst.Mol. Catal.2020,486, 110852pp.
17. Ling, S.; Ren, H.; Zhang, R.; Liu, Y.; Liu, B.; Cheng, R., Insights into the effect of vanadium on chromiumvanadium Phillips catalysts for the ethylene polymerization.Polyolefins J.2020,7(2), 61-78.
18. Wu, G.; Wang, J.; Liu, C.; Sun, M.; Zhang, L.; Ma, Y.; Cheng, R.; Ye, J., Transition metal-free, visible-light-mediated construction of α,β-diamino esters via decarboxylative radical addition at room temperature.Org. Chem. Front.2019,6(13), 2245-2249.
19. Ma, Y.; Yao, X.; Zhang, L.; Ni, P.; Cheng, R.; Ye, J., Direct arylation of α-amino C(sp3)-H bonds by convergent paired electrolysis.Angew. Chem., Int. Ed.2019,58(46), 16548-16552.
20. Lu, M.; Li, H.; Zou, C.; Li, J.; Liu, C.; Sun, M.; Ma, Y.; Cheng, R.; Ye, J., Primary amine catalyzed diastereo- and enantioselective Michael reaction of thiazolones and α, β-unsaturated ketones.Org. Biomol. Chem.2019,17(42), 9305-9312.
21. Liu, L.; Liu, Z.; Tang, S.; Cheng, R.; He, X.; Liu, B., What triggered the switching from ethylene-selective trimerization into tetramerization over the Cr/(2, 2'-dipicolylamine) catalysts?ACS Catal.2019,9(11), 10519-10527.
22. Jin, Y.; Liu, B.; Chen, L.; Guo, X.; Xu, L.; Zhu, Z.; Liu, Z.; Cheng, R., A Complexed initiating system AlCl3·phenetole/TiCl4·H2O with dominant synergistic effect for efficient synthesis of high molecular weight polyisobutylene.Polymers2019,11(12), doi:10.3390/polym11122121.
23. Jin, Y.; Dong, K.; Xu, L.; Guo, X.; Cheng, R.; Liu, B., Facile synthesis of medium molecular weight polyisobutylene with remarkable efficiency employing the complexed BF3·EtOH/TiCl4·H2O initiating system.Eur. Polym. J.2019,120, 109204.
24. Jin, Y.; Chen, L.; Guo, X.; Xu, L.; Zhu, Z.; Liu, Z.; Cheng, R.; Liu, B., A complexed initiating system AlCl3.bul.phenetole/TiCl4.bul.H2O with dominant synergistic effect for efficient synthesis of high molecular weight polyisobutylene.Polymers2019,11(12), 2121.
25. Zhu, L.; He, X.; Cheng, R.; Liu, Z.; Zhao, N.; Liu, B., Effects of Ti/Mg molar ratio on bi-supported SiO2/MgCl2(ethoxide type)/TiCl4catalysts in ethylene homopolymerization and ethylene/1-hexene copolymerization.Polyolefins J.2018,5(1), 1-13.
26. Liu, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Unraveling the effects of H2, N substituents and secondary ligands on Cr/PNP-catalyzed ethylene selective oligomerization.Organometallics2018,37(21), 3893-3900.
27. Li, Y.; Liu, Z.; Zhang, J.; Cheng, R.; Liu, B., Insights into the base-assisted acrylate formation from CO2/C2H4coupling by Pd- and Ni-catalyst: a DFT mechanistic study.ChemCatChem2018,10(24), 5669-5678.
28. Li, Y.; Liu, Z.; Cheng, R.; Liu, B., Mechanistic aspects of acrylic acid formation from CO2-ethylene coupling over palladium- and nickel-based catalysts.ChemCatChem2018,10(6), 1420-1430.
29. Fu, T.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., How can pH value during catalyst preparation affect the performance of vanadium-modified (SiO2/MgO/ MgCl2)·TiClxZiegler-Natta polyethylene catalysts.Polyolefins J.2018,5(1), 31-45.
30. Cheng, R.; Zhou, Y.; Hou, Q.; Liu, B., ZnO/SiO2-modified rare-earth-metal ternary catalyst bearing quaternary ammonium salts for synthesis of high molecular weight poly(propylene carbonate).Chin. J. Catal.2018,39(8), 1303-1310.
31. Sun, Q.; Wang, L.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., A Novel SiO2-supported fluorine modified chromium-vanadium bimetallic catalyst for ethylene polymerization and ethylene/1-hexene copolymerization.Macromol. React. Eng.2017,11(5), doi: 10.1002/mren.201600055.
32. Sun, Q.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., Effect of fluoride-modification on the phillips Cr/SiO2catalyst for ethylene polymerization.ChemCatChem2017,9(17), 3364-3373.
33. Sun, Q.; Cheng, R.; Liu, Z.; He, X.; Zhao, N.; Liu, B., Introduction of titanium species into fluorine-modified SiO2-supported Cr-V bimetallic catalyst for ethylene polymerization and ethylene/1-hexene copolymerization.Polyolefins J.2017,4(2), 221-234.
34. Liu, B.; Zhao, N.; Jin, Y.; Cheng, R.; He, X.; Liu, Z.; Liu, B., Effects of alkyl aluminum on sio2-supported silyl-chromate(Cr)/imido-vanadium(V) bimetallic catalysts for producing bimodal polyethylene.Macromol. React. Eng.2017,11(5), doi: 10.1002/mren.201700006.
35. Jin, Y.; Zhao, N.; Cheng, R.; Liu, B., Research progress of bimetallic catalysts for bimodal polyethylene synthesis.Huagong Xuebao2017,68(2), 485-495.
36. Jin, Y.; Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B., Remarkable promotion effect of sulfation over the SiO2-supported vanadium-oxide-based catalysts for UHMWPE.Macromol. Chem. Phys.2017,218(19), doi: 10.1002/macp.201700236.
37. Jin, Y.; Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Dong, D.; Bin, Y.; Chen, X.; Li, L.; Liu, B., One pot synthesis of bimodal UHMWPE/HDPE in-reactor blends with Cr/V bimetallic catalysts.J. Polym. Sci., Part A: Polym. Chem.2017,55(20), 3404-3412.
38. Jin, Y.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., The first vanadium-oxide-based UHMWPE catalyst supported on chemically modified silica gel.Macromol. Chem. Phys.2017,218(7), doi: 10.1002/macp.201600443.
39. Fu, T.; Liu, Z.; Cheng, R.; He, X.; Tian, Z.; Liu, B., Ethylene polymerization over MgCl2/SiO2Bi-supported Ziegler-Natta hybrid titanium/vanadium catalysts.Macromol. Chem. Phys.2017,218(13), doi: 10.1002/macp.201700027.
40. Cheng, R.; Liu, X.; Fang, Y.; Terano, M.; Liu, B., High-resolution29Si CP/MAS solid state NMR spectroscopy and DFT investigation on the role of geminal and single silanols in grafting chromium species over Phillips Cr/silica catalyst.Appl. Catal., A2017,543, 26-33.
41. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Vanadium modification effects on the (SiO2/MgO/MgCl2).TiClxZiegler-Natta polyethylene catalyst.Macromol. React. Eng.2016,10(3), 246-260.
42. Meng, Q.; Cheng, R.; Li, J.; Wang, T.; Liu, B., Copolymerization of CO2and propylene oxide using ZnGA/DMC composite catalyst for high molecular weight poly(propylene carbonate).J. CO2Util.2016,16, 86-96.
43. Li, J.; Cheng, R.; Ma, Y.; Liu, B., Imido-modified SiO2-supported Cr/Mo catalyst for ethylene polymerization.Hecheng Shuzhi Ji Suliao2016,33(1), 16-20.
44. Huang, F.; Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Optimization of the preparation temperature for the novel (SiO2/MgO/MgCl2)·TiClxZiegler-Natta polyethylene catalyst.Macromol. React. Eng.2016,10(6), 567-576.
45. Fu, T.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., Imido-modified SiO2-supported Ti/Mg Ziegler-Natta catalysts for ethylene polymerization and ethylene/1-hexene copolymerization.Polyolefins J.2016,3(2), 103-117.
46. Dong, K.; Liu, Z.; Cheng, R.; Liu, B., Synthesis of HR-PIB catalyzed by BF3-alcohol/ether complexes.Hecheng Shuzhi Ji Suliao2016,33(5), 1-6.
47. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Zhao, N.; Liu, B., Introduction of chromium species into the (SiO2/MgO/MgCl2)·TiClxZiegler-Natta catalyst for better catalytic performance.J. Organomet. Chem.2015,798, 299-310.
48. Wang, J.; Cheng, R.; He, X.; Liu, Z.; Tian, Z.; Liu, B., A Novel (SiO2/MgO/MgCl2)·TiClxZiegler-Natta catalyst for ethylene and ethylene/1-hexene polymerization.Macromol. Chem. Phys.2015,216(13), 1472-1482.
49. Pan, X.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Insight into the reaction mechanisms between CO2and epoxides over Zn(II) phenoxide catalytic system - A DFT study.J. Organomet. Chem.2015,775, 67-75.
50. Ma, Y.; Wang, L.; Liu, Z.; Cheng, R.; Zhong, L.; Yang, Y.; He, X.; Fang, Y.; Terano, M.; Liu, B., High-resolution XPS and DFT investigations into Al-modified Phillips CrOx/SiO2catalysts.J. Mol. Catal. A: Chem.2015,401, 1-12.
51. Ma, Y.; Cheng, R.; Li, J.; Zhong, L.; Liu, Z.; He, X.; Liu, B., Effect of Mo-modification over Phillips CrOx/SiO2catalyst for ethylene polymerization.J. Organomet. Chem.2015,791, 311-321.
52. Ma, Y.; Cheng, R.; Li, J.; Zhong, L.; Liu, Z.; He, X.; Liu, B., Effect of Mo-modification over Phillips CrOx/SiO2catalyst for ethylene polymerization.J. Organomet. Chem.2015,798, 317-327.
53. Cheng, R.; Xue, X.; Liu, W.; Zhao, N.; He, X.; Liu, Z.; Liu, B., Novel SiO2-supported chromium oxide(Cr)/vanadium oxide(V) bimetallic catalysts for production of bimodal polyethylene.Macromol. React. Eng.2015,9(5), 462-472.
54. Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B.; Zhang, R.; Gao, Y.; Zou, E.; Wang, S., Novel SiO2-supported silyl-chromate(Cr)/imido-vanadium(V) bimetallic catalysts producing polyethylene and ethylene/1-hexene copolymers with bimodal molecular-weight distribution.Macromol. Chem. Phys.2014,215(15), 1434-1445.
55. Zhao, N.; Cheng, R.; He, X.; Liu, Z.; Liu, B., A novel SiO2-supported Cr-V Bimetallic catalyst making polyethylene and ethylene/1-hexene copolymers with bimodal molecular weight Distribution.Macromol. Chem. Phys.2014,215(18), 1753-1766.
56. Yang, Y.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Mechanistic DFT Study on ethylene trimerization of chromium catalysts supported by a versatile pyrrole ligand system.Organometallics2014,33(10), 2599-2607.
57. Tang, S.; Liu, Z.; Zhan, X.; Cheng, R.; He, X.; Liu, B., 2D-QSPR/DFT studies of aryl-substituted PNP-Cr-based catalyst systems for highly selective ethylene oligomerization.J. Mol. Model.2014,20(3), 1-13.
58. Tang, S.; Liu, Z.; Zhan, X.; Cheng, R.; He, X.; Liu, B., 2D-QSPR studies on substituting PNP-Cr catalyst systems for highly selective ethylene oligomerization.Huagong Xuebao2014,65(1), 131-142.
59. Tang, S.; Liu, Z.; Yan, X.; Li, N.; Cheng, R.; He, X.; Liu, B., Kinetic studies on the pyrrole-Cr-based Chevron-Phillips ethylene trimerization catalyst system.Appl. Catal., A2014,481, 39-48.
60. Pan, X.; Liu, Z.; Cheng, R.; Jin, D.; He, X.; Liu, B., Experimental and theoretical studies on CO2and propylene oxide (PO) copolymerization catalyzed by ZnEt2-glycerine-Y(CCl3COO)3ternary catalyst.J. Organomet. Chem.2014,753, 63-71.
61. Liu, Z.; He, X.; Cheng, R.; Eisen, M. S.; Terano, M.; Scott, S. L.; Liu, B., Chromium catalysts for ethylene polymerization and oligomerization.Adv. Chem. Eng.2014,44(Catalysis and Kinetics), 127-191.
62. Liu, Z.; Cheng, R.; He, X.; Tian, Z.; Liu, B., Recent progress on molecular modeling of ethylene polymerization/oligomerization catalyzed by chromium-based catalysts.Huaxue Fanying Gongcheng Yu Gongyi2014,30(3), 218-228.
63. Zhong, L.; Liu, Z.; Cheng, R.; He, X.; Liu, B., Effect of fluorination of silica support on initiation of ethylene polymerization during induction period over Phillips catalyst.Huagong Xuebao2013,64(2), 539-546.
64. Zhang, S.; Cheng, R.; Dong, Q.; He, X.; Wang, Q.; Tang, Y.; Yu, Y.; Xie, K.; Da, J.; Terano, M.; Liu, B., Ethylene/1-hexene copolymerization with a novel SiO2-supported inorganic and organic hybrid chromium-based catalyst.Macromol. React. Eng.2013,7(6), 254-266.
65. Liu, Z.; Cheng, R.; He, X.; Liu, B., Reactivity and regioselectivity of methylacetylene cyclotrimerization over the Phillips Cr/silica catalyst: a DFT study.ACS Catal.2013,3(6), 1172-1183.
66. Li, L.; Wu, Y.; Dong, Q.; Hao, A.; Cheng, R.; Zhong, L.; Liu, B., Effect of Al-alkyl cocatalyst on ethylene polymerization behavior using silyl chromate (SC)/SiO2catalyst.Asia-Pac. J. Chem. Eng.2013,8(4), 539-546.
67. Cheng, R.; Liu, Z.; Zhong, L.; He, X.; Qiu, P.; Terano, M.; Eisen, M. S.; Scott, S. L.; Liu, B., Phillips Cr/Silica catalyst for ethylene polymerization.Adv. Polym. Sci.2013,257(Polyolefins: 50 Years after Ziegler and Natta I), 135-202.
68. Zhong, L.; Liu, Z.; Cheng, R.; Tang, S.; Qiu, P.; He, X.; Terano, M.; Liu, B., Active site transformation during the induction period of ethylene polymerization over the Phillips CrOx/SiO2catalyst.ChemCatChem2012,4(6), 872-881.
69. Zhang, S.; Zhao, N.; Wu, Y.; Dong, Q.; Wang, Q.; Tang, Y.; Yu, Y.; Da, J.; He, X.; Cheng, R.; Liu, B., Short chain branches distribution characterization of ethylene/1-hexene copolymers by using TREF+13C-NMR and TREF+SC methods.Macromol. Symp.2012,312, 63-71.
70. Zhang, S.; Dong, Q.; Cheng, R.; He, X.; Wang, Q.; Tang, Y.; Yu, Y.; Xie, K.; Da, J.; Liu, B., A novel SiO2-supported inorganic and organic hybrid chromium-based catalyst for ethylene polymerization.J. Mol. Catal. A: Chem.2012,358, 10-22.
71. Qiu, P.; Cheng, R.; Liu, Z.; Liu, B.; Tumanskii, B.; Eisen, M. S., Switching from ethylene polymerization to nonselective oligomerization over a homogeneous model catalyst: A triphenylsiloxy complex of chromium(VI).J. Organomet. Chem.2012,699, 48-55.
72. Liu, Z.; Cheng, R.; He, X.; Wu, X.; Liu, B., DFT functional benchmarking on the energy splitting of chromium spin states and mechanistic study of acetylene cyclotrimerization over the Phillips Cr(II)/silica catalyst.J. Phys. Chem. A2012,116(28), 7538-49.
73. Bai, X.; He, X.; Zhang, J.; Zhu, X.; Zhang, H.; Cheng, R.; Liu, B., Improvement of interfacial interaction, dispersion, and properties of chlorosulfonated polyethylene/SiO2nanocomposites using CSPE-g-SiO2nanoparticles synthesized under ultrasonics.Polym. Compos.2012,33(6), 940-950.
74. Yang, Y.; Liu, Z.; Zhong, L.; Qiu, P.; Dong, Q.; Cheng, R.; Vanderbilt, J.; Liu, B., Spin surface crossing between chromium(I)/sextet and chromium(III)/quartet without deprotonation in SNS-Cr mediated ethylene trimerization.Organometallics2011,30(19), 5297-5302.
75. Qiu, P.; Cheng, R.; Liu, B.; Tumanskii, B.; Batrice, R. J.; Botoshansky, M.; Eisen, M. S., A triphenylsiloxy complex of chromium(II) as a switchable catalyst for ethylene polymerization and nonselective oligomerization.Organometallics2011,30(8), 2144-2148.
76. Liu, Z.; Zhong, L.; Yang, Y.; Cheng, R.; Liu, B., DFT and CASPT2 study on the mechanism of ethylene dimerization over Cr(II)OH+cation.J. Phys. Chem. A2011,115(28), 8131-8141.
77. Wu, Y.; Zhang, H.; Dong, Q.; Yu, Y.; Tang, Y.; Cheng, R.; Liu, B., Ethylene and 1-hexene copolymerization using S-2 Cr-based catalyst.Hecheng Shuzhi Ji Suliao2010,27(2), 1-4.
78. Qi, Y.; Dong, Q.; Zhong, L.; Liu, Z.; Qiu, P.; Cheng, R.; He, X.; Vanderbilt, J.; Liu, B., Role of 1,2-dimethoxyethane in the transformation from ethylene polymerization to trimerization using chromium tris(2-ethylhexanoate)-based catalyst system: a DFT study.Organometallics2010,29(7), 1588-1602.
79. Li, X.; Cheng, R.; Luo, J.; Dong, Q.; He, X.; Li, L.; Yu, Y.; Da, J.; Liu, B., Experimental and theoretical studies on ethylene polymerization using SiO2-supported silyl chromate type catalysts prepared by a green method.J. Mol. Catal. A: Chem.2010,330(1-2), 56-65.
80. Cao, X.; Cheng, R.; Liu, Z.; Wang, L.; Dong, Q.; He, X.; Liu, B., DFT and PIO study of the influences of Mo valance state and surface hydroxyl on supported-MoOx catalysts for ethylene polymerization.J. Mol. Catal. A: Chem.2010,321(1-2), 50-60.
81. Qiu, P.; Li, X.; Zhang, S.; Cheng, R.; Dong, Q.; Liu, B.; Li, L.; Yu, Y.; Tang, Y.; Xie, J.; Wang, W., Supporting mechanism of non-toxic chromium(III) acetate on silica for preparation of Phillips ethylene polymerization catalysts.Asia-Pac. J. Chem. Eng.2009,4(5), 660-665.
82. Sun, J.; Zheng, M.; Wang, X.; Wang, A.; Cheng, R.; Li, T.; Zhang, T., Catalytic performance of activated carbon supported tungsten carbide for hydrazine decomposition.Catal. Lett.2008,123(1-2), 150-155.
83. Liu, B.; Cheng, R.; Liu, Z.; Qiu, P.; Zhang, S.; Taniike, T.; Terano, M.; Tashino, K.; Fujita, T., Experimental and computational approaches on the isospecific role of monoester-type internal electron donor for TiCl4/MgCl2Ziegler-Natta catalysts.Macromol. Symp.2007,260, 42-48.
84. Cheng, R.; Shu, Y.; Zheng, M.; Li, L.; Sun, J.; Wang, X.; Zhang, T., Molybdenum phosphide, a new hydrazine decomposition catalyst: Microcalorimetry and FTIR studies.J. Catal.2007,249(2), 397-400.
85. Cheng, R.; Shu, Y.; Li, L.; Zheng, M.; Wang, X.; Wang, A.; Zhang, T., Synthesis and characterization of high surface area molybdenum phosphide.Appl. Catal., A2007,316(2), 160-168.
86. Zheng, M.; Shu, Y.; Cheng, R.; Zhang, T., Synthesis and characterization of nano iron nitride for application in hydrazine decomposition.Prepr. Symp. - Am. Chem. Soc., Div. Fuel Chem.2006,51(2), 849-850.
87. Zheng, M.; Chen, X.; Cheng, R.; Li, N.; Sun, J.; Wang, X.; Zhang, T., Catalytic decomposition of hydrazine on iron nitride catalysts.Catal. Commun.2006,7(3), 187-191.
88. Cheng, R.; Shu, Y.; Li, L.; Sun, J.; Wang, X.; Zhang, T., CO adsorption on highly dispersed MoP/Al2O3prepared with citric acid.Thermochim. Acta2006,450(1-2), 42-46.
89. Zheng, M.; Cheng, R.; Chen, X.; Li, N.; Li, L.; Wang, X.; Zhang, T., A novel approach for CO-free H2production via catalytic decomposition of hydrazine.Int. J. Hydrogen Energy2005,30(10), 1081-1089.
90. Li, L.; Wang, X.; Zhao, X.; Zheng, M.; Cheng, R.; Zhou, L.; Zhang, T., Microcalorimetric studies of the iridium catalyst for hydrazine decomposition reaction.Thermochim. Acta2005,434(1-2), 119-124.
91. Cheng, R.; Li, N.; Zheng, M.; Li, L.; Wang, X.; Zhang, T., Preparation of molybdenum phosphide with high surface area.Cuihua Xuebao2005,26(7), 531-532.
92. Li, N.; Wang, A.; Zheng, M.; Wang, X.; Cheng, R.; Zhang, T., Probing into the catalytic nature of Co/sulfated zirconia for selective reduction of NO with methane.J. Catal.2004,225(2), 307-315.
93. Li, N.; Wang, A.; Wang, X.; Zheng, M.; Cheng, R.; Zhang, T., NO reduction by CH4in the presence of excess O2over Mn/sulfated zirconia catalysts.Appl. Catal., B2004,48(4), 259-265.
上一条:徐凯林 副教授下一条:彭江灵 副教授